Standard

A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis. / Neukermans, Sander; Hereijgers, Jonas; Vincent Ching, H. Y.; Samanipour, Mohammad; Van Doorslaer, Sabine; Hubin, Annick; Breugelmans, Tom.

In: Electrochemistry Communications, Vol. 97, 01.12.2018, p. 42-45.

Research output: Contribution to journalArticleResearchpeer-review

Harvard

APA

Vancouver

Neukermans S, Hereijgers J, Vincent Ching HY, Samanipour M, Van Doorslaer S, Hubin A et al. A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis. Electrochemistry Communications. 2018 Dec 1;97:42-45. https://doi.org/10.1016/j.elecom.2018.10.010

Author

Neukermans, Sander ; Hereijgers, Jonas ; Vincent Ching, H. Y. ; Samanipour, Mohammad ; Van Doorslaer, Sabine ; Hubin, Annick ; Breugelmans, Tom. / A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis. In: Electrochemistry Communications. 2018 ; Vol. 97. pp. 42-45.

BibTeX

@article{5e8af7487e584f479ffb1e1515f307d3,
title = "A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis",
abstract = "In this work, an improved in-situ EPR hydrodynamic electrochemical cell design is constructed and validated. The created platform enables the fast and accurate screening of new electrocatalytic materials, providing insights into their effects on radical products of a reaction. Furthermore, it is essential that the reaction kinetics are not influenced by the set-up and that mass transfer can be controlled. Our modular design allows for fast and easy replacement of parts and adjustments to electrodes in order to unravel the catalysts’ influence on radical formation. The proximity of the pseudo-reference electrode to the working electrode in combination with the flow and electrode positioning allows for good potential control. The POM housing allows easy manipulation of the channel and excludes the use of sealing agents.",
keywords = "Channel electrode, Electrochemical flow cell design, Electrochemical reduction, In-situ EPR spectroscopy, Radical detection",
author = "Sander Neukermans and Jonas Hereijgers and {Vincent Ching}, {H. Y.} and Mohammad Samanipour and {Van Doorslaer}, Sabine and Annick Hubin and Tom Breugelmans",
year = "2018",
month = "12",
day = "1",
doi = "10.1016/j.elecom.2018.10.010",
language = "English",
volume = "97",
pages = "42--45",
journal = "Electrochemistry Communications",
issn = "1388-2481",
publisher = "Elsevier Inc.",

}

RIS

TY - JOUR

T1 - A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis

AU - Neukermans, Sander

AU - Hereijgers, Jonas

AU - Vincent Ching, H. Y.

AU - Samanipour, Mohammad

AU - Van Doorslaer, Sabine

AU - Hubin, Annick

AU - Breugelmans, Tom

PY - 2018/12/1

Y1 - 2018/12/1

N2 - In this work, an improved in-situ EPR hydrodynamic electrochemical cell design is constructed and validated. The created platform enables the fast and accurate screening of new electrocatalytic materials, providing insights into their effects on radical products of a reaction. Furthermore, it is essential that the reaction kinetics are not influenced by the set-up and that mass transfer can be controlled. Our modular design allows for fast and easy replacement of parts and adjustments to electrodes in order to unravel the catalysts’ influence on radical formation. The proximity of the pseudo-reference electrode to the working electrode in combination with the flow and electrode positioning allows for good potential control. The POM housing allows easy manipulation of the channel and excludes the use of sealing agents.

AB - In this work, an improved in-situ EPR hydrodynamic electrochemical cell design is constructed and validated. The created platform enables the fast and accurate screening of new electrocatalytic materials, providing insights into their effects on radical products of a reaction. Furthermore, it is essential that the reaction kinetics are not influenced by the set-up and that mass transfer can be controlled. Our modular design allows for fast and easy replacement of parts and adjustments to electrodes in order to unravel the catalysts’ influence on radical formation. The proximity of the pseudo-reference electrode to the working electrode in combination with the flow and electrode positioning allows for good potential control. The POM housing allows easy manipulation of the channel and excludes the use of sealing agents.

KW - Channel electrode

KW - Electrochemical flow cell design

KW - Electrochemical reduction

KW - In-situ EPR spectroscopy

KW - Radical detection

UR - http://www.scopus.com/inward/record.url?scp=85054589348&partnerID=8YFLogxK

U2 - 10.1016/j.elecom.2018.10.010

DO - 10.1016/j.elecom.2018.10.010

M3 - Article

VL - 97

SP - 42

EP - 45

JO - Electrochemistry Communications

JF - Electrochemistry Communications

SN - 1388-2481

ER -

ID: 40443107